Semiconductor processing patterning methods and constructions

ABSTRACT

The invention includes semiconductor processing patterning methods and semiconductor constructions. A semiconductor processing patterning method includes forming a second composition resist layer over a different first composition resist layer. Overlapping portions of the first and second composition resist layers are exposed to actinic energy effective to change solubility of the exposed portions versus the unexposed portions of each of the first and second composition resist layers in a developer solution. The first and second composition resist layers are developed with the developer solution under conditions effective to remove the exposed portions of the first composition resist layer at a faster rate than removing the exposed portions of the second composition resist layer. Additional aspects and implementations are contemplated.

TECHNICAL FIELD

[0001] The present invention relates to semiconductor processing patterning methods and constructions.

BACKGROUND OF THE INVENTION

[0002] A continuing goal of semiconductor processing is increased miniaturization while maintaining high performance. Modern semiconductor processes are heavily reliant on photolithography when preparing semiconductors to achieve this goal.

[0003] Photolithography typically involves the following steps. Initially, a layer of resist is formed over a substrate. A reticle/mask is subsequently placed above the resist and radiation is allowed to pass through openings of the reticle/mask and contact the resist in patterns defined by the reticle/mask. Depending on whether the resist is a negative resist or a positive resist, the radiation renders exposed portions of the resist more or less soluble in a solvent relative to unexposed portions. The solvent is subsequently utilized to remove the more soluble portions of the resist while leaving the less soluble portions as a patterned mask. The mask pattern can be transferred to the underlying substrate with a suitable etch. Exemplary methods of prior art photolithography and a problem therewith are illustrated in FIGS. 1-3.

[0004] Referring first to FIG. 1, a semiconductor substrate 1 at one stage of semiconductor processing is shown that includes a bulk substrate 3, multilayers 4 (e.g., conductive, semiconductive and/or insulative layers) and a resist 5. To aid in interpretation of the claims that follow, the terms “semiconductive substrate” and “semiconductor substrate” are defined to mean any construction comprising semiconductive material, including, but not limited to, bulk semiconductive materials such as a semiconductive wafer (either alone or in assemblies comprising other materials thereon), and semiconductive material layers (either alone or in assemblies comprising other materials). The term “substrate” refers to any supporting structure, including, but not limited to, the semiconductive substrates described above.

[0005] Referring to FIG. 2, photoresist layer 5 has been processed to form masking blocks 7. It would be desirable that these masking blocks be of constant respective width in the illustrated cross-section from top to bottom. However in certain instances, the patterned photoresist tends to flare out at the bottoms/bases, as shown, forming what are commonly referred to as “footing”, depicted by feet 9.

[0006] Referring to FIG. 3, layers 4 have been etched using blocks 7 as an etch mask. As shown, feet 9 have functioned as part of that mask making the pattern of layers 4 substantially wider than the predominate width of blocks 7. In many instances, this is undesirable and/or difficult to predict or control.

SUMMARY OF THE INVENTION

[0007] The invention includes semiconductor processing patterning methods and semiconductor constructions. In one implementation, a semiconductor processing patterning method includes forming a second composition resist layer over a different first composition resist layer. Overlapping portions of the first and second composition resist layers are exposed to actinic energy effective to change solubility of the exposed portions versus the unexposed portions of each of the first and second composition resist layers in a developer solution. The first and second composition resist layers are developed with the developer solution under conditions effective to remove the exposed portions of the first composition resist layer at a faster rate than removing the exposed portions of the second composition resist layer.

[0008] In one implementation, a semiconductor construction includes a semiconductor substrate having a patterned resist mask received thereon. The resist mask includes a first composition resist portion and a different second composition resist portion received over the first composition resist portion. The first composition resist portion has opposing sidewalls in at least one cross section and the second composition resist portion has opposing sidewalls in the one cross section. At least a portion of the opposing sidewalls of the first composition resist portion are recessed laterally inward of at least a portion of the opposing sidewalls of the second composition resist portion.

[0009] Additional aspects and implementations are contemplated.

BRIEF DESCRIPTION OF THE DRAWINGS

[0010] Preferred embodiments of the invention are described below with reference to the following accompanying drawings

[0011]FIG. 1 is a diagrammatic cross-sectional view of a prior art semiconductor construction at one stage of processing.

[0012]FIG. 2 is a view of the FIG. 1 construction shown at a processing step subsequent to that of FIG. 1.

[0013]FIG. 3 is a view of the FIG. 2 construction shown at a processing step subsequent to that of FIG. 2.

[0014]FIG. 4 is a diagrammatic cross-sectional view of a semiconductor construction in accordance with an aspect of the present invention at one stage of processing.

[0015]FIG. 5 is a view of the FIG. 4 construction shown at a processing step subsequent to that of FIG. 4.

[0016]FIG. 6 is a view of the FIG. 5 construction shown at a processing step subsequent to that of FIG. 5.

[0017]FIG. 7 is an enlarged view of a portion of the FIG. 6 construction.

[0018]FIG. 8 is a view of the FIG. 6 construction shown at a processing step subsequent to that of FIG. 6.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0019] This disclosure of the invention is submitted in furtherance of the constitutional purposes of the U.S. Patent Laws “to promote the progress of science and useful arts” (Article 1, Section 8).

[0020] An exemplary semiconductor processing patterning method, in accordance with some aspects of the invention, is described with reference to FIGS. 4-8. Referring to FIG. 4, a wafer fragment 12 includes a bulk semiconductor substrate material 14, for example monocrystalline silicon. Of course other substrates, for example semiconductor-on-insulator substrates and other substrates whether existing or yet-to-be developed, could be utilized. One or more series of layers 16 are formed over material 14 for patterning. A first layer of resist 18 is formed over substrate 16/14. Resist layer 18 might be photosensitive or otherwise impacted by actinic energy (for example UV radiation, e-beam or other actinic energy) to change solubility of exposed versus unexposed portions in a suitable developer solution. Further, resist layer 18 might be a positive resist or a negative resist. In one implementation, the first layer of resist layer 18 is photosensitive to electromagnetic radiation at no greater than about 325 nm. By way of example, an exemplary thickness for layer 18 is less than about 700 Å.

[0021] A second layer of resist 20 is formed over first layer of resist 18. As shown in one implementation, second layer of resist 20 is formed “on” (meaning in direct physical contact) with first layer of resist 18. First layer of resist 18 and second layer of resist 20 can be of different compositions at least as initially formed. Further, second layer of resist 20 might be a positive resist or a negative resist.

[0022] In one implementation, resist layers 18 and 20 are both positive resist with layer 18 being provided to have a greater solubility in a developer solution than does second positive resist layer 20 at least after exposure to actinic energy effective to increase the solubility of each of the first and second positive resist layers in the developer solution. An exemplary material for first layer of resist 18 includes 1-methoxy-2-propanol, while an exemplary material for second layer of resist 20 includes cyclohexanone and 2-heptanone. An exemplary developer solution for such materials inlcudes tetramethyl ammonium hydroxide (TMAH).

[0023] Regardless of whether positive or negative resist are utilized, exemplary ways of modifying the erosion rate or the etch rate of a resist include adding to, subtracting from, or varying the composition of any of the components within the resist. For example, the use of, and/or type of resins, stabilizers, photoactive agents, polymers, molecular weight distribution, etc., can have an impact on the erosion or etch rate of a resist as is known and determined by people of skill in the art.

[0024] By way of example only, a specific exemplary positive resist material for first layer of resist 18 is SEPR-402 available from Shin-Etsu Chemical Company of Chiyoda-ku, Tokyo. Such is understood to include 1-methoxy-2-propanol, ethyl lactate and one or more proprietary components. After suitable exposure to actinic energy and development in a 21° C., 2.26 N/2.25% by weight TMAH in H₂O developer solution, SEPR-402 has an erosion or etch rate of about 500 Angstroms per minute.

[0025] Another example for first layer of resist 18 is M230Y available from the JSR Corporation of Sunnyvale, Calif. Such is understood to include 1-methoxy-2-propanol, ethyl lactate and various proprietary components. In the same developer solution described above, such has an erosion rate of about 300 Angstroms per minute. With such exemplary different etch rates, the M230Y might be used as an exemplary material for second layer of resist 20, with material SEPR-402 used as an exemplary material for first layer of resist 18. However, in certain circumstances it may be beneficial to utilize a material having an even slower etch rate for second layer of resist 20. By way of example only, such includes AR-360S manufactured by the JSR Corporation. Such is understood to include cyclohexanone, 2-heptanone and at least three proprietary components. Such material has an erosion or etch rate after exposure and development in the above developer solution of approximately 50 Angstroms per minute.

[0026] Other layers of resist and/or with other non-resist layers might also be utilized. For example, multi-level resist which typically combines resist and non-resist layers might be utilized. Regardless, in one preferred implementation, first layer of resist 18 has a thickness which is less than a total thickness of all layers received above it. In one implementation, first layer of resist 18 has a thickness which is less than or equal to about 50% (more preferably 25%, even more preferably 10%, and still more preferably 5%) of the total thickness of first layer of resist 18 and all layers received over first layer of resist 18. Further for example where the only other layer received above first layer of resist 18 is second layer of resist 20, the above-referred relationships apply relative to the thickness of second layer of resist 20.

[0027] Referring to FIG. 5, overlapping portions of first resist layer 18 and second resist layer 20 have been exposed to actinic energy effective to change solubility of the exposed portions versus the unexposed portions of each of the first and second resist layers 18 and 20 in a developer solution. For example, such could be conducted using a photolithographic mask/reticle, or by any other existing or yet-to-be developed techniques. In the particular illustrated and described implementation, the first and second layers of resist are both positive resists, and the illustrated overlapping portions 22 and 24 are masked while the remaining portions of layers 18 and 20 would be exposed to effectively increase their solubility in a developer solution. Of course, negative resist could be utilized where the opposite relationship would occur.

[0028] Referring to FIG. 6, first layer of resist 18 and second layer of resist 20 are developed with a suitable developer solution to form mask patterns 26 and 28 which comprise the first and second resist layers. In one implementation, the developing solution removes or etches the exposed portions, for example those exposed in FIG. 5, of first layer of resist 18 at a rate that is faster than the exposed portions of second layer of resist 20. Regardless, first resist layer 18 of the respective mask patterns 26 and 28 has respective opposing sidewalls 30 and 32 in at least one cross-section, for example that illustrated by FIG. 6. Further in one implementation, second resist layer 20 of the respective mask patterns 26 and 28 has respective opposing sidewall 34 and 36 in the one cross-section. As shown, at least a portion of opposing sidewalls 30 and 32 of first resist layer 18 are received laterally inward of at least a portion of opposing sidewalls 34 and 36 of second resist layer 20 in the one cross-section. As shown, the entirety of the opposing sidewalls 30 and 32 of first resist layer 18 in the one-cross-section are recessed laterally inward of opposing sidewalls 34 and 36 of second resist layer 20 in the one cross-section (FIGS. 6 and 7).

[0029] In one implementation, the opposing sidewalls of the first resist layer and the opposing sidewalls of the second resist layer are of different shapes in the one cross-section. For example and by way of example only, opposing sidewalls 34 and 36 of second resist layer 20 are generally straight along a substantial portion of their length, while opposing sidewalls 30 and 32 of first resist layer 18 are not. Further in one implementation, opposing sidewalls 30 and 32 of first resist layer 18 are at least partially curved in the one cross-section, with FIGS. 6 and 7 showing such sidewalls as being curved about their substantial entire lengths.

[0030] In addressing the issue or problem identified in the Background section above, one goal or object might be to reduce or eliminate the described footing. Where reduced footing or footing elimination occurs, a possible non-limiting theory is that one or both of the sidewall recessing, or faster etching rate of the first layer of resist, provides for the attack of any forming foot from underneath the foot as well as to a greater degree from its sides. The prior art processes may essentially be limited to the attack of only the top of the foot by developer solutions.

[0031] Referring to FIG. 8, material 16 of substrate 12 has been etched using mask patterns 26 and 28 as a mask. The artisan would, of course, select a suitable chemistry or chemistries in etching material 16, and at least some of one or more of resist materials 20 and 18 might also be etched to some degree in the process.

[0032] In one aspect, the invention also contemplates a semiconductor construction independent of the exemplary above-described methods. Such a construction comprises a semiconductor substrate having a patterned resist mask received thereon, for example as shown in FIG. 6. The resist mask comprises a first composition resist portion and a different second composition resist portion received over the first composition resist portion. The first composition resist portion has opposing sidewalls in at least one cross-section, and the second composition resist portion has opposing sidewalls in the one cross-section. At least a portion of the opposing sidewalls of the first composition resist portion are recessed laterally inward of at least a portion of the opposing sidewalls of the second composition resist portion. Exemplary and preferred attributes of the resist mask, first composition resist portion, second composition resist portion, and opposing sidewalls are as described above with respect to the methodical aspects.

[0033] In compliance with the statute, the invention has been described in language more or less specific as to structural and methodical features. It is to be understood, however, that the invention is not limited to the specific features shown and described, since the means herein disclosed comprise preferred forms of putting the invention into effect. The invention is, therefore, claimed in any of its forms or modifications within the proper scope of the appended claims appropriately interpreted in accordance with the doctrine of equivalents. 

The invention claimed is:
 1. A semiconductor processing patterning method, comprising: forming a first layer of resist over a substrate; forming a second layer of resist over the first layer of resist; exposing overlapping portions of the first and second resist layers to actinic energy effective to change solubility of the exposed portions versus the unexposed portions of each of the first and second resist layers in a developer solution; and after the exposing, developing the first and second layers of resist with the developer solution to form a mask pattern over the substrate comprising the first and second resist layers, the first resist layer of the mask pattern having opposing sidewalls in at least one cross section and the second resist layer of the mask pattern having opposing sidewalls in the one cross section, at least a portion of the opposing sidewalls of the first resist layer being received laterally inward of at least a portion of the opposing sidewalls of the second resist layer in the one cross section.
 2. The method of claim 1 wherein the first and second layers of resist are of different compositions as initially formed.
 3. The method of claim 1 wherein the first layer of resist is photosensitive to electromagnetic radiation at a wavelength of no greater than about 325 nm.
 4. The method of claim 1 wherein the second layer of resist is formed on the first layer of resist.
 5. The method of claim 1 wherein both the first layer of resist and the second layer of resist comprise negative resist.
 6. The method of claim 1 wherein both the first layer of resist and the second layer of resist comprise positive resist.
 7. The method of claim 1 wherein the actinic energy comprises UV radiation.
 8. The method of claim 1 wherein the actinic energy comprises an e-beam.
 9. The method of claim 1 wherein the developing comprises etching an exposed portion of the first layer of resist faster than an exposed portion of the second layer of resist.
 10. The method of claim 1 wherein the first layer of resist comprises at least one of 1-methoxy-2-propanol and ethyl lactate the second layer of resist comprises at least one of cyclohexanone and 2-heptanone.
 11. The method of claim 1 wherein the developer solution comprises TMAH.
 12. The method of claim 1 wherein the first layer of resist has a thickness which is less than a thickness of the second layer of resist.
 13. The method of claim 1 wherein the first layer of resist has a thickness which is less than a total thickness of all layers received over the first layer of resist.
 14. The method of claim 1 wherein the first layer of resist has a thickness which is less than or equal to about 50% of a total thickness of the first layer of resist and all layers received over the first layer of resist.
 15. The method of claim 1 wherein the first layer of resist has a thickness which is less than or equal to about 25% of a total thickness of the first layer of resist and all layers received over the first layer of resist.
 16. The method of claim 1 wherein the first layer of resist has a thickness which is less than or equal to about 10% of a total thickness of the first layer of resist and all layers received over the first layer of resist.
 17. The method of claim 1 wherein the first layer of resist has a thickness which is less than or equal to about 5% of a total thickness of the first layer of resist and all layers received over the first layer of resist.
 18. The method of claim 1 further comprising after the developing, etching material of the substrate using the mask pattern as a mask.
 19. The method of claim 1 wherein the opposing sidewalls of the first resist layer are at least partially curved in the one cross section.
 20. The method of claim 1 wherein the opposing sidewalls of the first resist layer and the opposing sidewalls of the second resist layer are of different shapes in the one cross section.
 21. The method of claim 1 wherein an entirety of the opposing sidewalls of the first resist layer in the one cross section are recessed laterally inward of the opposing sidewalls of the second resist layer in the one cross section.
 22. A semiconductor processing patterning method, comprising: forming a first positive resist layer over a substrate; forming a second positive resist layer over the first positive resist layer, the first and second positive resist layers being different in composition, the first positive resist layer having greater solubility in a developer solution than does the second positive resist layer at least after exposure to actinic energy effective to increase solubility of each of the first and second positive resist layers in the developer solution; exposing overlapping portions of the first and second positive resist layers to said effective actinic energy; and after the exposing, developing the first and second positive resist layers with the developer solution to form a mask pattern over the substrate comprising the first and second positive resist layers, the developing solution removing the exposed portions of the first positive resist layer at a faster rate than removing the exposed portions of the second positive resist layer effective to form the mask pattern to have opposing sidewalls of the first positive resist layer in at least one cross section at least a portion of which are recessed laterally inward of at least a portion of opposing sidewalls of the second positive resist layer in the one cross section.
 23. The method of claim 22 wherein the first positive resist layer is photosensitive to electromagnetic radiation at a wavelength of no greater than about 325 nm.
 24. The method of claim 22 wherein the second positive resist layer is formed on the first positive resist layer.
 25. The method of claim 22 wherein the actinic energy comprises UV radiation.
 26. The method of claim 22 wherein the actinic energy comprises an e-beam.
 27. The method of claim 22 wherein the first positive resist layer comprises 1-methoxy-2-propanol and the second positive resist layer comprises cyclohexanone and 2-heptanone.
 28. The method of claim 22 wherein the developer solution comprises TMAH.
 29. The method of claim 22 wherein the first positive resist layer has a thickness which is less than a thickness of the second positive resist layer.
 30. The method of claim 22 wherein the first positive resist layer has a thickness which is less than a total thickness of all layers received over the first positive resist layer.
 31. The method of claim 22 wherein the first positive resist layer has a thickness which is from about 25% to about 50% of a total thickness of the first positive resist layer and all layers received over the first positive resist layer.
 32. The method of claim 22 wherein the first positive resist layer has a thickness which is from about 5% to about 10% of a total thickness of the first positive resist layer and all layers received over the first positive resist layer.
 33. The method of claim 22 wherein the first positive resist layer has a thickness which is less than about 5% of a total thickness of the first positive resist layer and all layers received over the first positive resist layer.
 34. The method of claim 22 further comprising after the developing, etching material of the substrate using the mask pattern as a mask.
 35. The method of claim 22 wherein the opposing sidewalls of the first positive resist layer are at least partially curved in the one cross section.
 36. The method of claim 22 wherein an entirety of the opposing sidewalls of the first positive resist layer are recessed laterally inward of the opposing sidewalls of the second positive resist layer in the one cross section.
 37. A semiconductor processing patterning method, comprising: forming a second composition resist layer over a different first composition resist layer; exposing overlapping portions of the first and second composition resist layers to actinic energy effective to initiate formation of a mask pattern having a second mask block over a first mask block, wherein solubility of the first mask block is greater than solubility of the second mask block in a developer solution; and developing the first and second composition resist layers with the developer solution under conditions effective to remove the material of the first mask block at a faster rate than removing the material of the second mask block and form the mask pattern.
 38. The method of claim 37 wherein the first composition resist layer is photosensitive to electromagnetic radiation at a wavelength of no greater than about 325 nm.
 39. The method of claim 37 wherein the second composition resist layer is formed on the first composition resist layer.
 40. The method of claim 37 wherein the second mask block is formed on the first mask block.
 41. The method of claim 37 wherein the actinic energy comprises UV radiation.
 42. The method of claim 37 wherein the actinic energy comprises an e-beam.
 43. The method of claim 37 wherein both the first composition resist layer and the second composition resist layer comprise negative resist.
 44. The method of claim 37 wherein both the first composition resist layer and the second composition resist layer comprise positive resist
 45. The method of claim 37 wherein the first composition resist layer comprises 1-methoxy-2-propanol and the second composition resist-layer comprises cyclohexanone and 2-heptanone.
 46. The method of claim 37 wherein the developer solution comprises TMAH.
 47. The method of claim 37 wherein the first mask block has a thickness which is less than a thickness of the second mask block.
 48. The method of claim 37 wherein the first composition resist layer has a thickness which is less than a total thickness of all layers received over the first composition resist layer.
 49. The method of claim 37 wherein the first composition resist layer has a thickness which is less than or equal to about 50% of a total thickness of the first composition resist layer and all layers received over the first composition resist layer.
 50. The method of claim 37 wherein the first composition resist layer has a thickness which is less than or equal to about 25% of a total thickness of the first composition resist layer and all layers received over the first composition resist layer.
 51. The method of claim 37 wherein the first composition resist layer has a thickness which is less than or equal to about 10% of a total thickness of the first composition resist layer and all layers received over the first composition resist layer.
 52. The method of claim 37 wherein the first composition resist layer has a thickness which is less than or equal to about 5% of a total thickness of the first composition resist layer and all layers received over the first composition resist layer.
 53. The method of claim 37 wherein the mask pattern comprises opposing sidewalls of the first mask block in at least one cross section at least a portion of which are recessed laterally inward of at least a portion of the opposing sidewalls of the second mask block in the one cross section.
 54. The method of claim 53 wherein the opposing sidewalls of the first mask block are at least partially curved in the one cross section.
 55. The method of claim 53 wherein the opposing sidewalls of the first mask block and the opposing sidewalls of the second mask block are of different shapes in the one cross section.
 56. The method of claim 53 wherein an entirety of the opposing sidewalls of the first mask block in the one cross section are recessed laterally inward of the opposing sidewalls of the second mask block in the one cross section.
 57. The method of claim 53 further comprising after the developing, etching material of the substrate using the mask pattern as a mask.
 58. A semiconductor construction comprising a semiconductor substrate having a patterned resist mask received thereon, the resist mask comprising a first composition resist portion and a different second composition resist portion received over the first composition resist portion, the first composition resist portion having opposing sidewalls in at least one cross section and the second composition resist portion having opposing sidewalls in the one cross section, at least a portion of the opposing sidewalls of the first composition resist portion being recessed laterally inward of at least a portion of the opposing sidewalls of the second composition resist portion.
 59. The semiconductor construction of claim 58 wherein the second composition resist portion is received on the first composition resist portion.
 60. The semiconductor construction of claim 58 wherein both the first composition resist portion and the second composition resist portion comprise negative resist.
 61. The semiconductor construction of claim 58 wherein both the first composition resist portion and the second composition resist portion comprise positive resist.
 62. The semiconductor construction of claim 58 wherein the first composition resist portion has a thickness which is less than a thickness of the second composition resist portion.
 63. The semiconductor construction of claim 58 wherein the first composition resist portion has a thickness which is less than a total thickness of all layers received over the first composition resist portion.
 64. The semiconductor construction of claim 58 wherein the first composition resist portion has a thickness which is less than or equal to about 50% of a total thickness of the first composition resist portion and all layers received over the first composition resist portion.
 65. The semiconductor construction of claim 58 wherein the first composition resist portion has a thickness which is less than or equal to about 25% of a total thickness of the first composition resist portion and all layers received over the first composition resist portion.
 66. The semiconductor construction of claim 58 wherein the first composition resist portion has a thickness which is less than or equal to about 10% of a total thickness of the first composition resist portion and all layers received over the first composition resist portion.
 67. The semiconductor construction of claim 58 wherein the first composition resist portion has a thickness which is less than or equal to about 5% of a total thickness of the first composition resist portion and all layers received over the first composition resist portion.
 68. The semiconductor construction of claim 58 wherein the opposing sidewalls of the first composition resist portion are at least partially curved in the one cross section.
 69. The semiconductor construction of claim 58 wherein the opposing sidewalls of the first composition resist portion and the opposing sidewalls of the second composition resist portion are of different shapes in the one cross section.
 70. The semiconductor construction of claim 58 wherein an entirety of the opposing sidewalls of the first composition resist portion in the one cross section are recessed laterally inward of the opposing sidewalls of the second composition resist portion in the one cross section. 